An aryl-phosphonate appended macrocyclic platform for lanthanide based bimodal imaging agents

Matteo P. Placidi; Jörn Engelmann; Louise S. Natrajan; Nikos K. Logothetis; Goran Angelovski

doi:10.1039/C1CC14437E

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Chemical Communications

Issue 41, 2011

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An aryl-phosphonate appended macrocyclic platform for lanthanide based bimodal imaging agents

Matteo P. Placidi , Jörn Engelmann , Louise S. Natrajan , Nikos K. Logothetis and Goran Angelovski

Chem. Commun., 2011,47, 11534-11536

DOI: 10.1039/C1CC14437E
Received 21 Jul 2011, Accepted 19 Sep 2011
First published on the web 26 Sep 2011

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Abstract
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Four ligand systems have been prepared whose characteristics are well suited to the design of bimodal MRI and luminescence probes. The lanthanide complexes display high relaxivities and luminescence quantum yields. These properties are retained at higher magnetic fields and in a range of competitive environments including model extracellular medium and cultured cells.