Issue 39, 2011
From the journal:

Chemical Communications

PtCl2/XPhos: A highly efficient and readily available catalyst for the hydrosilylation of propargylic alcohols†

Mark G. McLaughlina  and  Matthew J. Cook*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Queen's University Belfast, Belfast, Northern Ireland
E-mail: m.cook@qub.ac.uk
Fax: +44 (0)28 90976524
Tel: +44 (0)28 90974682

Abstract

A highly regioselective hydrosilylation of propargylic alcohols has been developed using an in situ prepared PtCl2/XPhos catalyst system. The reaction is tolerant of many functional groups and exhibits excellent regio and geometric selectivity.

Graphical abstract: PtCl2/XPhos: A highly efficient and readily available catalyst for the hydrosilylation of propargylic alcohols

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Article information

DOI
https://doi.org/10.1039/C1CC14433B
Article type
Communication
Submitted
21 Jul 2011
Accepted
24 Aug 2011
First published
12 Sep 2011

Chem. Commun., 2011,47, 11104-11106

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PtCl2/XPhos: A highly efficient and readily available catalyst for the hydrosilylation of propargylic alcohols

M. G. McLaughlin and M. J. Cook, Chem. Commun., 2011, 47, 11104 DOI: 10.1039/C1CC14433B

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