Polyacetylene bearing a pendant rotaxane moiety with an optically active wheel component was synthesized to realize reversible structural control of its helical structure by position control of the wheel component. Polyacetylene formed a one-handed helical structure only when the optically active wheel component moved close to the main chain.
F. Ishiwari, K. Nakazono, Y. Koyama and T. Takata, Chem. Commun., 2011, 47, 11739 DOI: 10.1039/C1CC14404A
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