Jump to main content
Jump to site search

Issue 38, 2011
Previous Article Next Article

Reducing the conformational flexibility of carbohydrates: locking the 6-hydroxyl group by cyclopropanes

Author affiliations

Abstract

The 6-hydroxyl group of hexopyranosides was stereochemically locked by the spiroannelation of a cyclopropane unit at C-5. The corresponding glucose and mannose derivatives were prepared and their behaviour in glycosidation reactions was studied.

Graphical abstract: Reducing the conformational flexibility of carbohydrates: locking the 6-hydroxyl group by cyclopropanes

Back to tab navigation

Supplementary files

Publication details

The article was received on 05 Jul 2011, accepted on 09 Aug 2011 and first published on 05 Sep 2011


Article type: Communication
DOI: 10.1039/C1CC14025F
Citation: Chem. Commun., 2011,47, 10782-10784
  •   Request permissions

    Reducing the conformational flexibility of carbohydrates: locking the 6-hydroxyl group by cyclopropanes

    C. Brand, M. Granitzka, D. Stalke and D. B. Werz, Chem. Commun., 2011, 47, 10782
    DOI: 10.1039/C1CC14025F

Search articles by author

Spotlight

Advertisements