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Issue 41, 2011
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Ruthenium-catalyzed cyclization/transfer hydrogenation of 1,6-diynes: unprecedented mode of alcohol activationvia metallacyclopentatriene

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Abstract

The first transfer-hydrogenative cyclization of 1,6-diynes that leads to exocyclic dienes was developed using a ruthenium catalyst and MeOH as a H2 surrogate.

Graphical abstract: Ruthenium-catalyzed cyclization/transfer hydrogenation of 1,6-diynes: unprecedented mode of alcohol activationvia metallacyclopentatriene

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Publication details

The article was received on 23 Jun 2011, accepted on 09 Sep 2011 and first published on 19 Sep 2011


Article type: Communication
DOI: 10.1039/C1CC13744A
Citation: Chem. Commun., 2011,47, 11552-11554
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    Ruthenium-catalyzed cyclization/transfer hydrogenation of 1,6-diynes: unprecedented mode of alcohol activationvia metallacyclopentatriene

    K. Yamashita, Y. Nagashima, Y. Yamamoto and H. Nishiyama, Chem. Commun., 2011, 47, 11552
    DOI: 10.1039/C1CC13744A

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