Issue 34, 2011
From the journal:

Chemical Communications

Stereocontrolled synthesis of 20,21-dihydro N-methylwelwitindolinone B isothiocyanate†

Vikram Bhata  and  Viresh H. Rawal*a  

* Corresponding authors

a Department of Chemistry, The University of Chicago, 5735 South Ellis Avenue, Chicago, USA
E-mail: vrawal@uchicago.edu
Fax: +1 773 702 0805
Tel: +1 773 702 2194

Abstract

Described is a concise synthesis of the 20,21-dihydro analog of N-methylwelwitindolinone B isothiocyanate, wherein a cationic homoallyl to cyclopropylmethyl rearrangement is circumvented by hydrogenation of the offending double bond.

Graphical abstract: Stereocontrolled synthesis of 20,21-dihydro N-methylwelwitindolinone B isothiocyanate

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Article information

DOI
https://doi.org/10.1039/C1CC13498A
Article type
Communication
Submitted
14 Jun 2011
Accepted
14 Jul 2011
First published
27 Jul 2011

Chem. Commun., 2011,47, 9705-9707

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Stereocontrolled synthesis of 20,21-dihydro N-methylwelwitindolinone B isothiocyanate

V. Bhat and V. H. Rawal, Chem. Commun., 2011, 47, 9705 DOI: 10.1039/C1CC13498A

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