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Issue 35, 2011
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Stereoselective approaches to 2,3,6-trisubstituted piperidines. An enantiospecific synthesis of quinolizidine (−)-217A

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Abstract

The enantiospecific and diastereocontrolled total synthesis of alkaloid (−)-217A is described that employs a stepwise [3+3] annelation strategy and a piperidine 2,3-cyclopropanation–ring opening reaction as the key steps.

Graphical abstract: Stereoselective approaches to 2,3,6-trisubstituted piperidines. An enantiospecific synthesis of quinolizidine (−)-217A

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Publication details

The article was received on 24 May 2011, accepted on 20 Jul 2011 and first published on 05 Aug 2011


Article type: Communication
DOI: 10.1039/C1CC13048J
Citation: Chem. Commun., 2011,47, 9804-9806
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    Stereoselective approaches to 2,3,6-trisubstituted piperidines. An enantiospecific synthesis of quinolizidine (−)-217A

    N. C. Mancey, N. Sandon, A. Auvinet, R. J. Butlin, W. Czechtizky and J. P. A. Harrity, Chem. Commun., 2011, 47, 9804
    DOI: 10.1039/C1CC13048J

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