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Issue 32, 2011
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Assembly of 2D ionic layers by reaction of alkali halides with the organic electrophile 7,7,8,8-tetracyano-p-quinodimethane (TCNQ)

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Abstract

Sublimation of alkali halides (NaCl and LiCl) onto a pre-assembled hydrogen-bonded layer of TCNQ on Au(111) resulted in the formation of 2D ionic layers via a direct charge-transfer reaction without involvement of the substrate. The presented approach allows for the fabrication of different ionic layers, decoupled from the substrate and offering new, potentially interesting properties.

Graphical abstract: Assembly of 2D ionic layers by reaction of alkali halides with the organic electrophile 7,7,8,8-tetracyano-p-quinodimethane (TCNQ)

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Publication details

The article was received on 29 Apr 2011, accepted on 21 Jun 2011 and first published on 13 Jul 2011


Article type: Communication
DOI: 10.1039/C1CC12519B
Citation: Chem. Commun., 2011,47, 9146-9148
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    Assembly of 2D ionic layers by reaction of alkali halides with the organic electrophile 7,7,8,8-tetracyano-p-quinodimethane (TCNQ)

    C. Wäckerlin, C. Iacovita, D. Chylarecka, P. Fesser, T. A. Jung and N. Ballav, Chem. Commun., 2011, 47, 9146
    DOI: 10.1039/C1CC12519B

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