Issue 28, 2011
From the journal:

Chemical Communications

Post-polymerization functionalization of linear polyglycidol with diethyl vinylphosphonate†

Jens Köhler,a   Helmut Keul*a  and  Martin Möller*a  

* Corresponding authors

a Institute of Technical and Macromolecular Chemistry, RWTH Aachen University and DWI an der RWTH Aachen e.V., Pauwelsstr. 8, 52056 Aachen, Germany
E-mail: keul@dwi.rwth-aachen.de, moeller@dwi.rwth-aachen.de
Fax: +49 241-8023301
Tel: +49 241-8026438

Abstract

In this communication we report on the base catalyzed Michael addition of the hydroxy methyl side groups in polyglycidol to diethyl vinyl phosphonate. Hydrolysis of the diethyl phosphonato ethyl side groups with bromotrimethylsilane leads to a new class of polyglycidols with pendant phosphonic acid groups.

Graphical abstract: Post-polymerization functionalization of linear polyglycidol with diethyl vinylphosphonate

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Article information

DOI
https://doi.org/10.1039/C1CC12484F
Article type
Communication
Submitted
28 Apr 2011
Accepted
24 May 2011
First published
10 Jun 2011

Chem. Commun., 2011,47, 8148-8150

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Post-polymerization functionalization of linear polyglycidol with diethyl vinylphosphonate

J. Köhler, H. Keul and M. Möller, Chem. Commun., 2011, 47, 8148 DOI: 10.1039/C1CC12484F

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