Issue 24, 2011

“Clickable” pillar[5]arenes

Abstract

Introduction of bulky substituents such as benzyl and pyrenyl groups using click reactions inhibited or slowed the rotation of the units on the NMR chemical shift timescale. The perpyrenylated pillar[5]arene showed a thermally-responsive excimer emission, but a unit model of the perpyrenylated pillar[5]arene did not exhibit such a response.

Graphical abstract: “Clickable” pillar[5]arenes

Supplementary files

Article information

Article type
Communication
Submitted
01 Apr 2011
Accepted
20 Apr 2011
First published
23 May 2011

Chem. Commun., 2011,47, 6927-6929

“Clickable” pillar[5]arenes

T. Ogoshi, R. Shiga, M. Hashizume and T. Yamagishi, Chem. Commun., 2011, 47, 6927 DOI: 10.1039/C1CC11864A

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