Issue 16, 2011
From the journal:

Chemical Communications

Chiral properties of tetrathiatriarylmethyl spin probes†

Benoît Driesschaert,ab   Raphaël Robiette,a   Fabio Lucaccioni,a   Bernard Gallezb  and  Jacqueline Marchand-Brynaert*a  

* Corresponding authors

a Institute of Condensed Matter and Nanosciences (IMCN), Molecules, Solids and Reactivity (MOST), Université Catholique de Louvain, Place Louis Pasteur 1, B-1348 Louvain-la-Neuve, Belgium
E-mail: jacqueline.marchand@uclouvain.be
Fax: +32 (0) 10 47 41 68
Tel: +32 (0) 10 47 27 40

b Louvain Drug Research Institute (LDRI), Biomedical Magnetic Resonance Section, Université Catholique de Louvain, Avenue Mounier 73.40, B-1200 Bruxelles, Belgium

Abstract

We report that tetrathiatriarylmethyl (trityl) EPR probes are chiral molecules at room temperature, the two stereoisomers that differ in their helicity being configurationally stable enough to be separated and stored independently.

Graphical abstract: Chiral properties of tetrathiatriarylmethyl spin probes

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Article information

DOI
https://doi.org/10.1039/C1CC10988J
Article type
Communication
Submitted
19 Feb 2011
Accepted
25 Feb 2011
First published
15 Mar 2011

Chem. Commun., 2011,47, 4793-4795

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Chiral properties of tetrathiatriarylmethyl spin probes

B. Driesschaert, R. Robiette, F. Lucaccioni, B. Gallez and J. Marchand-Brynaert, Chem. Commun., 2011, 47, 4793 DOI: 10.1039/C1CC10988J

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