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Issue 20, 2011
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Fluorous tagging of DABCO through halogen bonding: recyclable catalyst for the Morita–Baylis–Hillman reaction

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Abstract

The halogen-bonded adduct between DABCO and two molecules of perfluorooctyl iodide (DABCO·(C8F17I)2) acts as a recyclable organocatalyst for the Morita–Baylis–Hillman reaction. This “supramolecular fluorous catalyst” is readily accessible and can be recovered by simple precipitation/filtration.

Graphical abstract: Fluorous tagging of DABCO through halogen bonding: recyclable catalyst for the Morita–Baylis–Hillman reaction

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Publication details

The article was received on 14 Feb 2011, accepted on 28 Mar 2011 and first published on 15 Apr 2011


Article type: Communication
DOI: 10.1039/C1CC10869G
Citation: Chem. Commun., 2011,47, 5855-5857
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    Fluorous tagging of DABCO through halogen bonding: recyclable catalyst for the Morita–Baylis–Hillman reaction

    S. Dordonne, B. Crousse, D. Bonnet-Delpon and J. Legros, Chem. Commun., 2011, 47, 5855
    DOI: 10.1039/C1CC10869G

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