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Issue 23, 2011
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New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides

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Abstract

A heptanuclear iron carbonyl cluster, [Fe3(CO)11(μ-H)]2Fe(DMF)4 (4), is found to be a highly efficient catalyst for the reduction of various carboxamides by 1,2-bis(dimethylsilyl)benzene (BDSB), which makes possible reducing the amount of the catalyst, shortening the reaction time, and lowering the reaction temperatures.

Graphical abstract: New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides

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Publication details

The article was received on 01 Feb 2011, accepted on 26 Apr 2011 and first published on 12 May 2011


Article type: Communication
DOI: 10.1039/C1CC10636H
Citation: Chem. Commun., 2011,47, 6581-6583
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    New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides

    H. Tsutsumi, Y. Sunada and H. Nagashima, Chem. Commun., 2011, 47, 6581
    DOI: 10.1039/C1CC10636H

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