Issue 12, 2011
From the journal:

Chemical Communications

Iron-catalyzed direct amination of azoles using formamides or amines as nitrogen sources in air†

Jian Wang,a   Ji-Ting Hou,a   Jun Wen,a   Ji Zhang*a  and  Xiao-Qi Yu*a  

* Corresponding authors

a Key Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu, P. R. China
E-mail: xqyu@tfol.com
Fax: (+86)28-85415886

Abstract

A new iron-catalyzed, direct C–H amination of azoles at C2 has been developed by using formamides or amines as nitrogen sources. Imidazole is the only additive in the catalyst system and oxygen in air is employed during the transformation process.

Graphical abstract: Iron-catalyzed direct amination of azoles using formamides or amines as nitrogen sources in air

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Article information

DOI
https://doi.org/10.1039/C0CC05811D
Article type
Communication
Submitted
27 Dec 2010
Accepted
27 Jan 2011
First published
16 Feb 2011

Chem. Commun., 2011,47, 3652-3654

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Iron-catalyzed direct amination of azoles using formamides or amines as nitrogen sources in air

J. Wang, J. Hou, J. Wen, J. Zhang and X. Yu, Chem. Commun., 2011, 47, 3652 DOI: 10.1039/C0CC05811D

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