Issue 8, 2011
From the journal:

Chemical Communications

Platinadithiolene-conjugated pyrylium salt with strong intramolecular donor–acceptor interaction†

Koya Prabhakara Rao,a   Tetsuro Kusamoto,a   Ryota Sakamoto,a   Yuki Yamamoto,a   Shoko Kume,a   Masayuki Nihei,b   Hiroki Oshiob  and  Hiroshi Nishihara*a  

* Corresponding authors

a Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
E-mail: nisihara@chems.u-tokyo.ac.jp
Fax: +81 (03)5841-8063
Tel: +81 (03)5841-4346

b Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba 305-8571, Japan

Abstract

Protonation of a new platinum complex, Pt(1-pdtAq)(tBu2bpy), where 1-pdtAq is 1-(phenyldithiolenethynyl)anthraquinone, afforded a cyclized structure, [Pt(1-pdtPyl)(tBu2bpy)]+, with a unique electronic structure due to intense intramolecular charge transfer.

Graphical abstract: Platinadithiolene-conjugated pyrylium salt with strong intramolecular donor–acceptor interaction

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C0CC04762G
Article type
Communication
Submitted
03 Nov 2010
Accepted
26 Nov 2010
First published
15 Dec 2010

Chem. Commun., 2011,47, 2330-2332

Permissions

Request permissions

Platinadithiolene-conjugated pyrylium salt with strong intramolecular donor–acceptor interaction

K. P. Rao, T. Kusamoto, R. Sakamoto, Y. Yamamoto, S. Kume, M. Nihei, H. Oshio and H. Nishihara, Chem. Commun., 2011, 47, 2330 DOI: 10.1039/C0CC04762G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements