Issue 9, 2011
From the journal:

Chemical Communications

An achiral manganese salen catalyst encapsulated in a peptidic phosphonate homochiral solid for the enantioselective formation of diols by consecutive epoxidation and hydration reactions†

Anat Miloa  and  Ronny Neumann*a  

* Corresponding authors

a Department of Organic Chemistry, Weizmann Institute of Science, Rehovot, Israel
E-mail: Ronny.Neumann@weizmann.ac.il

Abstract

An insoluble, porous, amorphous, homochiral material based on a polypeptide titanium–phosphonate scaffold with an encapsulated achiralMnIII–salen was prepared and characterized. Consecutive epoxidation and hydration of styrene and its derivatives by aqueous hypochlorite in THF showed the highly enantioselective (>99%) formation of styrene diol derivatives.

Graphical abstract: An achiral manganese salen catalyst encapsulated in a peptidic phosphonate homochiral solid for the enantioselective formation of diols by consecutive epoxidation and hydration reactions

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C0CC04205F
Article type
Communication
Submitted
03 Oct 2010
Accepted
14 Dec 2010
First published
11 Jan 2011

Chem. Commun., 2011,47, 2535-2537

Permissions

Request permissions

An achiral manganese salen catalyst encapsulated in a peptidic phosphonate homochiral solid for the enantioselective formation of diols by consecutive epoxidation and hydration reactions

A. Milo and R. Neumann, Chem. Commun., 2011, 47, 2535 DOI: 10.1039/C0CC04205F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements