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Issue 1, 2011
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Copper-mediated cross-coupling of 1,1-dibromo-1-alkenes with dialkyl phosphites: a convenient synthesis of 1-alkenylphosphonates

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Abstract

An efficient and stereoselective procedure for the preparation of E-1-alkenylphosphonates by copper-mediated cross-coupling between 1,1-dibromo-1-alkenes and dialkyl phosphites is reported. The reaction allows for formal substitution of both bromine atoms, respectively, by an hydrogen and a dialkoxyphosphoryl.

Graphical abstract: Copper-mediated cross-coupling of 1,1-dibromo-1-alkenes with dialkyl phosphites: a convenient synthesis of 1-alkenylphosphonates

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Publication details

The article was received on 27 May 2010, accepted on 18 Jun 2010 and first published on 12 Jul 2010


Article type: Communication
DOI: 10.1039/C0CC01617A
Citation: Chem. Commun., 2011,47, 179-181
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    Copper-mediated cross-coupling of 1,1-dibromo-1-alkenes with dialkyl phosphites: a convenient synthesis of 1-alkenylphosphonates

    G. Evano, K. Tadiparthi and F. Couty, Chem. Commun., 2011, 47, 179
    DOI: 10.1039/C0CC01617A

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