Spray desorption collection of free fatty acids onto a solid phase microextraction fiber for trap grease analysis in biofuel production

Abstract

Spray desorption collection (SDC) is a sample collection and preparation method that allows for the collection of soluble chemical compounds directly from solid surfaces. Here the analysis of trap grease, a potential biofuel feedstock, is demonstrated by combining SDC with solid phase micro-extraction (SPME) collection followed by direct GC-MS analysis. The SPME fiber collects droplets of solvent, which has picked up analytes from the solid sample surface. It is found that the SDC–SPME combination is a simple and convenient method to collect sample components from surfaces when they are less volatile than heptanoic acid, while the collection efficiency of highly volatile compounds is increasingly reduced due to the purging effect of the nebulising gas. In a real trap grease analysis the SDC–SPME method was able to analyze both the longer chain fatty acids in the sample, important for energy production evaluation of the sample, as well as volatile sample components down to pentanoic acid, which may add to off-odours produced during biofuel use.