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Issue 38, 2011
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Pentametallic lanthanide-alkoxide square-based pyramids: high energy barrier for thermal relaxation in a holmium single molecule magnet

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Abstract

Pentametallic Ln complexes of formula [Ln5O(OiPr)13] have been made, where LnIII = Sm, Gd, Tb, Ho and Er; slow magnetisation relaxation to 33 K is observed for the Ho complex with an energy barrier of ca. 400 K.

Graphical abstract: Pentametallic lanthanide-alkoxide square-based pyramids: high energy barrier for thermal relaxation in a holmium single molecule magnet

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Publication details

The article was received on 12 Jul 2011, accepted on 11 Aug 2011 and first published on 01 Sep 2011


Article type: Communication
DOI: 10.1039/C1CC14186D
Citation: Chem. Commun., 2011,47, 10587-10589
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    Pentametallic lanthanide-alkoxide square-based pyramids: high energy barrier for thermal relaxation in a holmium single molecule magnet

    R. J. Blagg, F. Tuna, E. J. L. McInnes and R. E. P. Winpenny, Chem. Commun., 2011, 47, 10587
    DOI: 10.1039/C1CC14186D

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