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Issue 20, 2011
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“On water” sp3–sp2 cross-couplings between benzylic and alkenyl halides

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Abstract

Organic-solvent-free cross-couplings between benzylic and alkenyl halides have been developed. Various alkenyl halides can be efficiently benzylated by combining the precursor halides in the presence of Zn dust and a Pd catalyst at room temperature, in water as the only medium.

Graphical abstract: “On water” sp3–sp2 cross-couplings between benzylic and alkenyl halides

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Publication details

The article was received on 23 Feb 2011, accepted on 18 Mar 2011 and first published on 12 Apr 2011


Article type: Communication
DOI: 10.1039/C1CC11087J
Citation: Chem. Commun., 2011,47, 5717-5719
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    “On water” sp3–sp2 cross-couplings between benzylic and alkenyl halides

    V. Krasovskaya, A. Krasovskiy, A. Bhattacharjya and B. H. Lipshutz, Chem. Commun., 2011, 47, 5717
    DOI: 10.1039/C1CC11087J

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