Issue 11, 2010
From the journal:

New Journal of Chemistry

(MeQn2SiH)Fe[N(SiMe3)2]2 (Qn = 8-quinolyl): an unusual δ-agostic iron complex containing an η1-SiH interaction†

Jian Yang,a   Meg Fasuloa  and  T. Don Tilley*a  

* Corresponding authors

a Department of Chemistry, University of California, Berkeley, California 94720, USA
E-mail: tdtilley@berkeley.edu

Abstract

Reaction of MeQn2SiH (Qn = 8-quinolyl) (1) with Fe[N(SiMe3)2]2 at room temperature afforded (MeQn2SiH)Fe[N(SiMe3)2]2 (2), which is an unusual example of a δ-agostic iron complex containing an η1-H–Si interaction. Treatment of 2 with excess 3-pentanone at 60 °C produced MeQn2SiOCHEt2 (3) in ca. 80% yield.

Graphical abstract: (MeQn2SiH)Fe[N(SiMe3)2]2 (Qn = 8-quinolyl): an unusual δ-agostic iron complex containing an η1-SiH interaction

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Article information

DOI
https://doi.org/10.1039/C0NJ00554A
Article type
Letter
Submitted
15 Jul 2010
Accepted
10 Aug 2010
First published
20 Sep 2010

New J. Chem., 2010,34, 2528-2529

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(MeQn2SiH)Fe[N(SiMe3)2]2 (Qn = 8-quinolyl): an unusual δ-agostic iron complex containing an η1-SiH interaction

J. Yang, M. Fasulo and T. D. Tilley, New J. Chem., 2010, 34, 2528 DOI: 10.1039/C0NJ00554A

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