Issue 45, 2010
From the journal:

Dalton Transactions

A new approach to internal Lewis pairs featuring a phosphenium acid and a pyridine base†

Allison L. Brazeau,a   Christine A. Caputo,a   Caleb D. Martin,a   Nathan D. Jonesa  and  Paul J. Ragogna*a  

* Corresponding authors

a Department of Chemistry, The University of Western Ontario, 1151 Richmond St., London, ON, Canada
E-mail: pragogna@uwo.ca
Fax: + 1 519 661 3022
Tel: +1 519 661 2111

Abstract

A bis(imino)acenaphthene (BIAN) ligand containing a pendant Lewis base has been used as a new framework to support a N-heterocyclic phosphenium cation (NHP). Reactivity studies demonstrate the ability of the ligand to act as a Lewis base, while the phosphorus centre provides a Lewis acidic site, giving new opportunities in NHP chemistry.

Graphical abstract: A new approach to internal Lewis pairs featuring a phosphenium acid and a pyridine base

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Article information

DOI
https://doi.org/10.1039/C0DT01029D
Article type
Paper
Submitted
16 Aug 2010
Accepted
07 Sep 2010
First published
21 Oct 2010

Dalton Trans., 2010,39, 11069-11073

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A new approach to internal Lewis pairs featuring a phosphenium acid and a pyridine base

A. L. Brazeau, C. A. Caputo, C. D. Martin, N. D. Jones and P. J. Ragogna, Dalton Trans., 2010, 39, 11069 DOI: 10.1039/C0DT01029D

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