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Issue 38, 2010
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Lacunary tungstotellurates(IV): [Te2W17O61]12−, [Te2W16O58(OH)2]14− and [Te2W18O62(OH)2]10−

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Abstract

A simple procedure is reported for the isolation of the new lacunary tungstotellurate(IV) [Te2W17O61]12− (1a) in multi-gram quantities, with 125Te and 183W NMR spectroscopy indicating retention of the solid state structure in solution. The structurally related polyanions [Te2W16O58(OH)2]14− (2a) and [Te2W18O62(OH)2]10− (2b) were also isolated.

Graphical abstract: Lacunary tungstotellurates(iv): [Te2W17O61]12−, [Te2W16O58(OH)2]14− and [Te2W18O62(OH)2]10−

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Publication details

The article was received on 26 May 2010, accepted on 09 Aug 2010 and first published on 31 Aug 2010


Article type: Communication
DOI: 10.1039/C0DT00547A
Citation: Dalton Trans., 2010,39, 8872-8874
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    Lacunary tungstotellurates(IV): [Te2W17O61]12−, [Te2W16O58(OH)2]14− and [Te2W18O62(OH)2]10−

    C. Ritchie, K. G. Alley and C. Boskovic, Dalton Trans., 2010, 39, 8872
    DOI: 10.1039/C0DT00547A

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