Issue 20, 2010

A family of double-bowl pseudometallocalix[6]arene discs

Abstract

We report the synthesis and magnetic characterisation of a series of planar [M7] (M = NiII, ZnII) disc complexes [Ni7(OH)6(L1)6](NO3)2 (1), [Ni7(OH)6(L1)6](NO3)2·2MeOH (2), [Ni7(OH)6(L1)6](NO3)2·3MeNO2 (3), [Ni7(OH)6(L2)6](NO3)2·2MeCN (4), [Zn7(OH)6(L1)6](NO3)2·2MeOH·H2O (5) and [Zn7(OH)6(L1)6](NO3)2·3MeNO2 (6) (where HL1 = 2-iminomethyl-6-methoxy-phenol, HL2 = 2-iminomethyl-4-bromo-6-methoxy-phenol). Each member exhibits a double-bowl pseudo metallocalix[6]arene topology whereby the individual [M7] units form molecular host cavities which are able to accommodate various guest molecules (MeCN, MeNO2 and MeOH). Magnetic susceptibility measurements carried out on complexes 1 and 4 indicate weak exchange between the NiII centres.

Graphical abstract: A family of double-bowl pseudo metallocalix[6]arene discs

Supplementary files

Article information

Article type
Paper
Submitted
17 Dec 2009
Accepted
30 Jan 2010
First published
10 Mar 2010

Dalton Trans., 2010,39, 4809-4816

A family of double-bowl pseudo metallocalix[6]arene discs

S. T. Meally, C. McDonald, G. Karotsis, G. S. Papaefstathiou, E. K. Brechin, P. W. Dunne, P. McArdle, N. P. Power and L. F. Jones, Dalton Trans., 2010, 39, 4809 DOI: 10.1039/B926704B

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