Issue 1, 2010
From the journal:

Dalton Transactions

New alkylzinc complexes with bulky tris(triazolyl)borate ligands: Surprising water stability and reactivity†

Mukesh Kumar,a   Elizabeth T. Papish,*a   Matthias Zellerb  and  Allen D. Hunterb  

* Corresponding authors

a Department of Chemistry, Drexel University, 3141 Chestnut St., Philadelphia, PA, USA
E-mail: elizabeth.papish@drexel.edu

b Department of Chemistry, Youngstown State University, 1 University Plaza, Youngstown, OH

Abstract

Bulky alkylzinc complexes, (TtztBu,Me)ZnMe and (TtztBu,Me)ZnEt, show remarkable stability towards water and both complexes crystallize with one molecule of adventitious water hydrogen bonded to two triazole rings; in contrast the less bulky complex, (TtzPh,Me)ZnEt, reacts with water to yield (TtzPh,Me)2Zn.

Graphical abstract: New alkylzinc complexes with bulky tris(triazolyl)borate ligands: Surprising water stability and reactivity

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Article information

DOI
https://doi.org/10.1039/B918328K
Article type
Communication
Submitted
11 Sep 2009
Accepted
14 Oct 2009
First published
27 Oct 2009

Dalton Trans., 2010,39, 59-61

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New alkylzinc complexes with bulky tris(triazolyl)borate ligands: Surprising water stability and reactivity

M. Kumar, E. T. Papish, M. Zeller and A. D. Hunter, Dalton Trans., 2010, 39, 59 DOI: 10.1039/B918328K

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