Issue 11, 2010
From the journal:

CrystEngComm

Chiral crystallization of ether- and imide-bridged biphenyl compounds without any outside chiral source†

Takafumi Kinuta,a   Tomohiro Sato,b   Nobuo Tajima,c   Reiko Kuroda,*bd   Yoshio Matsubara*a  and  Yoshitane Imai*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka, Osaka 577-8502, Japan
E-mail: y-imai@apch.kindai.ac.jp, y-matsu@apch.kindai.ac.jp
Fax: +81 06 6727 2024
Tel: +81 06 6730 5880x5241

b JST ERATO-SORST Kuroda Chiromorphology Team, 4-7-6, Komaba, Meguro-ku, Tokyo 153-0041, Japan
E-mail: ckuroda@mail.ecc.u-tokyo.ac.jp.

c Graduate School of Pure and Applied Sciences, Tsukuba University, 1-1-1 Tenodai, Tsukuba, Ibaraki 305-8571, Japan

d Department of Life Sciences, Graduate School of Arts and Sciences, The University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo 153-8902, Japan

Abstract

Although both enantiomers of two-substituted ether- and imide-bridged biphenyl compounds 1–3 are present in equal amounts at equilibrium in a solution, chiral crystals composed of one of the axially chiral enantiomers could be isolated by crystallization from the solution without any outside chiral source.

Graphical abstract: Chiral crystallization of ether- and imide-bridged biphenyl compounds without any outside chiral source

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Article information

DOI
https://doi.org/10.1039/C0CE00055H
Article type
Communication
Submitted
01 Apr 2010
Accepted
18 Jun 2010
First published
02 Aug 2010

CrystEngComm, 2010,12, 3483-3486

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Chiral crystallization of ether- and imide-bridged biphenyl compounds without any outside chiral source

T. Kinuta, T. Sato, N. Tajima, R. Kuroda, Y. Matsubara and Y. Imai, CrystEngComm, 2010, 12, 3483 DOI: 10.1039/C0CE00055H

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