Issue 11, 2010
From the journal:

CrystEngComm

Di[2,6-bis(5-phenylpyrazol-3-yl)pyridine]Co(II): an old coordination mode for a novel supramolecular assembly†

Todd R. Scicluna,a   Benjamin H. Fraser,a   Nicole T. Gorham,d   Jonathan G. MacLellan,a   Massimiliano Massi,*b   Brian W. Skelton,c   Timothy G. St Pierred  and  Robert C. Woodwardd  

* Corresponding authors

a School of Chemistry, Monash University, Box 23, Clayton, Australia

b Department of Chemistry, Curtin University of Technology, GPO Box U1987, Perth, Australia
E-mail: m.massi@curtin.edu.au
Fax: +61-8-9266-2300
Tel: +61-8-9266-2838

c School of Biomedical, Biomolecular and Chemical Sciences, The University of Western Australia, Stirling Highway Crawley, Australia

d School of Physics, The University of Western Australia, Stirling Highway Crawley, Australia

Abstract

CoCl2 was treated with 1, 2, and 6 eq. of 2,6-bis(5-phenylpyrazol-3-yl)pyridine (H2L) yielding respectively the monosubstituted [Co(H2L)Cl2], the disubstituted [Co(H2L)2][PF6]2, and a supramolecular assembly formed by a central disubstituted octahedral complex and four more hydrogen bonded peripheral ligands, [{Co(H2L)2}(H2L)4][PF6]2, as illustrated by X-ray crystal structure analysis.

Graphical abstract: Di[2,6-bis(5-phenylpyrazol-3-yl)pyridine]Co(II): an old coordination mode for a novel supramolecular assembly

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Article information

DOI
https://doi.org/10.1039/C0CE00036A
Article type
Communication
Submitted
25 Mar 2010
Accepted
04 Jun 2010
First published
06 Jul 2010

CrystEngComm, 2010,12, 3422-3424

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Di[2,6-bis(5-phenylpyrazol-3-yl)pyridine]Co(II): an old coordination mode for a novel supramolecular assembly

T. R. Scicluna, B. H. Fraser, N. T. Gorham, J. G. MacLellan, M. Massi, B. W. Skelton, T. G. St Pierre and R. C. Woodward, CrystEngComm, 2010, 12, 3422 DOI: 10.1039/C0CE00036A

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