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Issue 47, 2010
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Development of the first well-defined tungsten oxo alkyl derivatives supported on silica by SOMC: towards a model of WO3/SiO2 olefin metathesis catalyst

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Abstract

A well-defined, silica-supported tungsten oxo alkyl species prepared by the surface organometallic chemistry approach displays high and sustained activity in propene metathesis. Remarkably, its catalytic performances outpace those of the parent imido derivative, underlining the importance of the oxo ligand in the design of robust catalysts.

Graphical abstract: Development of the first well-defined tungsten oxo alkyl derivatives supported on silica by SOMC: towards a model of WO3/SiO2 olefin metathesis catalyst

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Publication details

The article was received on 12 Jul 2010, accepted on 13 Oct 2010 and first published on 27 Oct 2010


Article type: Communication
DOI: 10.1039/C0CC02507K
Citation: Chem. Commun., 2010,46, 8944-8946
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    Development of the first well-defined tungsten oxo alkyl derivatives supported on silica by SOMC: towards a model of WO3/SiO2 olefin metathesis catalyst

    E. Mazoyer, N. Merle, A. D. Mallmann, J. Basset, E. Berrier, L. Delevoye, J. Paul, C. P. Nicholas, R. M. Gauvin and M. Taoufik, Chem. Commun., 2010, 46, 8944
    DOI: 10.1039/C0CC02507K

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