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Issue 46, 2010
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1,4-Addition of silicon dienoates to α,β-unsaturated aldehydes catalyzed by in situ-generated silicon Lewis acid

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Abstract

In situ-generated silyl methide species (R3Si–CTf2R′) effectively catalyzed the reaction of β-substituted α,β-unsaturated aldehydes with silicon dienoates such as 3-bromo-2-TESO-furan to give the corresponding γ-adducts with excellent 1,4-selectivity and good anti selectivity.

Graphical abstract: 1,4-Addition of silicon dienoates to α,β-unsaturated aldehydes catalyzed by in situ-generated silicon Lewis acid

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Publication details

The article was received on 08 Jul 2010, accepted on 28 Sep 2010 and first published on 22 Oct 2010


Article type: Communication
DOI: 10.1039/C0CC02438D
Citation: Chem. Commun., 2010,46, 8728-8730
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    1,4-Addition of silicon dienoates to α,β-unsaturated aldehydes catalyzed by in situ-generated silicon Lewis acid

    H. Yanai, A. Takahashi and T. Taguchi, Chem. Commun., 2010, 46, 8728
    DOI: 10.1039/C0CC02438D

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