Issue 29, 2010
From the journal:

Chemical Communications

Introduction of cavities up to 4 nm into a hierarchically-assembled metal–organic framework using an angular, tetratopic ligand†

Wenjuan Zhuang,a   Shengqian Ma,b   Xi-Sen Wang,a   Daqiang Yuan,a   Jian-Rong Li,a   Dan Zhaoa  and  Hong-Cai Zhou*a  

* Corresponding authors

a Department of Chemistry, Texas A&M University, College Station, Texas 77843, USA
E-mail: zhou@mail.chem.tamu.edu
Fax: +1-979-845 1595
Tel: +1-979-845 4034

b Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, USA

Abstract

Cavities up to 4 nm have been introduced into a hierarchically-assembled metal–organic framework by adopting an angular, semi-flexible tetratopic ligand. The resulting MOF possesses permanent porosity and exhibits stepwise sorption isotherms for O2 and N2 gases.

Graphical abstract: Introduction of cavities up to 4 nm into a hierarchically-assembled metal–organic framework using an angular, tetratopic ligand

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Article information

DOI
https://doi.org/10.1039/C0CC00779J
Article type
Communication
Submitted
05 Apr 2010
Accepted
28 May 2010
First published
23 Jun 2010

Chem. Commun., 2010,46, 5223-5225

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Introduction of cavities up to 4 nm into a hierarchically-assembled metal–organic framework using an angular, tetratopic ligand

W. Zhuang, S. Ma, X. Wang, D. Yuan, J. Li, D. Zhao and H. Zhou, Chem. Commun., 2010, 46, 5223 DOI: 10.1039/C0CC00779J

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