Oxidative dimerization of N-protected and free indole derivatives toward 3,3′-biindoles via Pd-catalyzed direct C–H transformations

Yang Li; Wen-Hua Wang; Shang-Dong Yang; Bi-Jie Li; Chun Feng; Zhang-Jie Shi

doi:10.1039/C0CC00486C

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Oxidative dimerization of N-protected and free indole derivatives toward 3,3′-biindoles viaPd-catalyzed direct C–H transformations†

Yang Li,^ab Wen-Hua Wang,^ab Shang-Dong Yang,^ab Bi-Jie Li,^ab Chun Feng^ab and Zhang-Jie Shi*^ab

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* Corresponding authors

^a Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 10087, China

^b State Key Laboratory of Organometallic Chemistry, SIOC, CAS, Shanghai 200032, China
E-mail: zshi@pku.edu.cn

Abstract

An oxidative homo dimerization of N-protected and free indole derivatives toward bioactive 3,3′-linked biindolyl scaffolds via Pd-catalyzed direct C–H transformations was first successfully demonstrated.

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DOI: https://doi.org/10.1039/C0CC00486C
Article type: Communication
Submitted: 19 Mar 2010
Accepted: 23 Apr 2010
First published: 19 May 2010

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Chem. Commun., 2010,46, 4553-4555

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Oxidative dimerization of N-protected and free indole derivatives toward 3,3′-biindoles via Pd-catalyzed direct C–H transformations

Y. Li, W. Wang, S. Yang, B. Li, C. Feng and Z. Shi, Chem. Commun., 2010, 46, 4553 DOI: 10.1039/C0CC00486C

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Chemical Communications

Oxidative dimerization of N-protected and free indole derivatives toward 3,3′-biindoles viaPd-catalyzed direct C–H transformations†

Abstract

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Oxidative dimerization of N-protected and free indole derivatives toward 3,3′-biindoles via Pd-catalyzed direct C–H transformations

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