Interaction of hydrogen with accessible metal sites in the metal–organic frameworks M2(dhtp) (CPO-27-M; M = Ni, Co, Mg)

Pascal D. C. Dietzel; Peter A. Georgiev; Juergen Eckert; Richard Blom; Thierry Strässle; Tobias Unruh

doi:10.1039/C0CC00091D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Interaction of hydrogen with accessible metal sites in the metal–organic frameworks M₂(dhtp) (CPO-27-M; M = Ni, Co, Mg)†

Pascal D. C. Dietzel,*^a Peter A. Georgiev,^b Juergen Eckert,^c Richard Blom,^a Thierry Strässle^d and Tobias Unruh^e

Author affiliations

* Corresponding authors

^a SINTEF Materials and Chemistry, P.O. Box 124 Blindern, N-0314 Oslo, Norway
E-mail: pascal.dietzel@sintef.no
Fax: +47 22067350
Tel: +47 98243958

^b Department of Structural Chemistry, University of Milan, 21 Via G. Venezian, I-20133 Milan, Italy
E-mail: pageorgiev@yahoo.co.uk

^c Materials Research Laboratory, University of California, Santa Barbara, USA
E-mail: juergen@mrl.ucsb.edu
Fax: +1 805 893 8797
Tel: +1 805 893 8247

^d Laboratory for Neutron Scattering, ETH Zurich & Paul Scherrer Institut, 5232 Villigen PSI, Switzerland
E-mail: thierry.straessle@psi.ch

^e FRM-II, Technische Universität München, 84748 Garching, Germany
E-mail: tobias.unruh@frm2.tum.de

Abstract

Hydrogen molecules adsorbed in the nickel, cobalt, and magnesium analogs of the CPO-27 metal–organic framework at low loadings interact significantly more strongly than those adsorbed successively as a consequence of the strong interaction of hydrogen with the coordinatively unsaturated metal cations in the framework.

Download options Please wait...

Supplementary files

Experimental procedures, calculation of the hypothetical surface area and comparison with experimental data from nitrogen adsorption, reversibility of hydrogen adsorption at 77 K. PDF (2590K)

Article information

DOI: https://doi.org/10.1039/C0CC00091D
Article type: Communication
Submitted: 23 Feb 2010
Accepted: 06 May 2010
First published: 28 May 2010

Download Citation

Chem. Commun., 2010,46, 4962-4964

Permissions

Request permissions

Interaction of hydrogen with accessible metal sites in the metal–organic frameworks M₂(dhtp) (CPO-27-M; M = Ni, Co, Mg)

P. D. C. Dietzel, P. A. Georgiev, J. Eckert, R. Blom, T. Strässle and T. Unruh, Chem. Commun., 2010, 46, 4962 DOI: 10.1039/C0CC00091D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications