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Issue 27, 2010
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Interaction of hydrogen with accessible metal sites in the metal–organic frameworks M2(dhtp) (CPO-27-M; M = Ni, Co, Mg)

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Abstract

Hydrogen molecules adsorbed in the nickel, cobalt, and magnesium analogs of the CPO-27 metal–organic framework at low loadings interact significantly more strongly than those adsorbed successively as a consequence of the strong interaction of hydrogen with the coordinatively unsaturated metal cations in the framework.

Graphical abstract: Interaction of hydrogen with accessible metal sites in the metal–organic frameworks M2(dhtp) (CPO-27-M; M = Ni, Co, Mg)

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Publication details

The article was received on 23 Feb 2010, accepted on 06 May 2010 and first published on 28 May 2010


Article type: Communication
DOI: 10.1039/C0CC00091D
Citation: Chem. Commun., 2010,46, 4962-4964
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    Interaction of hydrogen with accessible metal sites in the metal–organic frameworks M2(dhtp) (CPO-27-M; M = Ni, Co, Mg)

    P. D. C. Dietzel, P. A. Georgiev, J. Eckert, R. Blom, T. Strässle and T. Unruh, Chem. Commun., 2010, 46, 4962
    DOI: 10.1039/C0CC00091D

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