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Issue 29, 2010
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Amido-stabilized rare-earth metal mixed methyl methylidene complexes

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Abstract

Donor(thf)-induced tetramethylaluminate cleavage of Ln(AlMe4)2(NSiMe3AriPr) as well as the reaction of (LnMe3)n (Ln = Y, Ho, Lu) with HNSiMe3AriPr in tetrahydrofuran affords unprecedented trinuclear rare-earth metal tetramethyl methylidene complexes which act as Schrock-type nucleophilic carbenes and methyl transfer agents.

Graphical abstract: Amido-stabilized rare-earth metal mixed methyl methylidene complexes

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Publication details

The article was received on 16 Feb 2010, accepted on 09 Jun 2010 and first published on 23 Jun 2010


Article type: Communication
DOI: 10.1039/C003206A
Citation: Chem. Commun., 2010,46, 5346-5348
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    Amido-stabilized rare-earth metal mixed methyl methylidene complexes

    M. Zimmermann, D. Rauschmaier, K. Eichele, K. W. Törnroos and R. Anwander, Chem. Commun., 2010, 46, 5346
    DOI: 10.1039/C003206A

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