Issue 33, 2010
From the journal:

Chemical Communications

A novel tricyanoruthenium(iii) building block for the construction of bimetallic coordination polymers†

Jing Xiang,a   Wai-Lun Man,a   Junfang Guo,a   Shek-Man Yiu,a   Gene-Hsiang Lee,b   Shie-Ming Peng,b   Guancheng Xu,c   Song Gao*c  and  Tai-Chu Lau*a  

* Corresponding authors

a Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon Tong, Hong Kong, China
E-mail: bhtclau@cityu.edu.hk
Fax: (+852)27887406

b Department of Chemistry, National Taiwan University, Taipei 106, Taiwan

c State Key Laboratory of Rare Earth Materials Chemistry and Applications and PKU-HKU Joint Laboratory on Rare Earth Materials and Bioinorganic Chemistry, Peking University, Beijing 100871, China
E-mail: gaosong@pku.edu.cn
Fax: (+86) 10-62751708

Abstract

Reaction of excess cyanide with a ruthenium(VI) nitrido complex bearing a tridentate Schiff base ligand produces a novel tricyanoruthenium(III) complex in which nucleophilic substitution of an imine hydrogen of the Schiff base by cyanide has occurred, this complex is a useful building block for the construction of 3d-RuIII magnetic materials.

Graphical abstract: A novel tricyanoruthenium(iii) building block for the construction of bimetallic coordination polymers

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Article information

DOI
https://doi.org/10.1039/C001732A
Article type
Communication
Submitted
29 Jan 2010
Accepted
18 Jun 2010
First published
26 Jul 2010

Chem. Commun., 2010,46, 6102-6104

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A novel tricyanoruthenium(III) building block for the construction of bimetallic coordination polymers

J. Xiang, W. Man, J. Guo, S. Yiu, G. Lee, S. Peng, G. Xu, S. Gao and T. Lau, Chem. Commun., 2010, 46, 6102 DOI: 10.1039/C001732A

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