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Issue 23, 2010
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Bifunctional AgOAc-catalyzed asymmetric reactions

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Abstract

The discovery and progress of new bifunctional AgOAc-based catalysts for asymmetric reactions is described. In this bifunctional procedure, AgOAc acts as an efficient Lewis acid catalyst as well as a base through the deprotonation of active hydrogen promoted by acetate. The bifunctional strategy offers a great opportunity to establish new fundamentals for stereoselective construction of C–C as well as C–N bonds.

Graphical abstract: Bifunctional AgOAc-catalyzed asymmetric reactions

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Publication details

The article was received on 18 Jan 2010, accepted on 13 Apr 2010 and first published on 11 May 2010


Article type: Feature Article
DOI: 10.1039/C001089H
Citation: Chem. Commun., 2010,46, 4043-4051
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    Bifunctional AgOAc-catalyzed asymmetric reactions

    Q. Chen, D. Wang and Y. Zhou, Chem. Commun., 2010, 46, 4043
    DOI: 10.1039/C001089H

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