Issue 16, 2010
From the journal:

Chemical Communications

Cs9[(γ-PW10O36)2Ru4O5(OH)(H2O)4], a new all-inorganic, soluble catalyst for the efficient visible-light-driven oxidation of water†

Claire Besson,ab   Zhuangqun Huang,b   Yurii V. Geletii,b   Sheri Lense,b   Kenneth I. Hardcastle,b   Djamaladdin G. Musaev,b   Tianquan Lian,b   Anna Proustac  and  Craig L. Hill*b  

* Corresponding authors

a Institut Parisien de Chimie Moléculaire, UMR CNRS 7201, UPMC Univ. Paris 06, Case 42, 4 place Jussieu, 75005 Paris, France

b Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta GA 30322, USA
E-mail: chill@emory.edu
Fax: +1 404-727-6076
Tel: +1 404-727-6611

c Institut Universitaire de France, 103 bd Saint-Michel, 75005 Paris, France

Abstract

The tetraruthenium-substituted polyoxometalate Cs9[(γ-PW10O36)2Ru4O5(OH)(H2O)4] was synthesized and structurally, spectroscopically and electrochemically characterized; it was shown to be a catalyst for visible-light-induced water oxidation.

Graphical abstract: Cs9[(γ-PW10O36)2Ru4O5(OH)(H2O)4], a new all-inorganic, soluble catalyst for the efficient visible-light-driven oxidation of water

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Article information

DOI
https://doi.org/10.1039/B926064A
Article type
Communication
Submitted
11 Dec 2009
Accepted
10 Feb 2010
First published
25 Feb 2010

Chem. Commun., 2010,46, 2784-2786

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Cs9[(γ-PW10O36)2Ru4O5(OH)(H2O)4], a new all-inorganic, soluble catalyst for the efficient visible-light-driven oxidation of water

C. Besson, Z. Huang, Y. V. Geletii, S. Lense, K. I. Hardcastle, D. G. Musaev, T. Lian, A. Proust and C. L. Hill, Chem. Commun., 2010, 46, 2784 DOI: 10.1039/B926064A

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