Synthesis and reactivity of ferrocenyl functionalized Sn/S cages

Christopher Pöhlker; Inga Schellenberg; Rainer Pöttgen; Stefanie Dehnen

doi:10.1039/B923871A

skip RSC | ChemSpider | Feedback

Home > Journals > Chemical Communications > Synthesis and reactivit...

Authors & Referees | Librarians

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Chemical Communications

Issue 15, 2010

More about this Journal
Editorial Board
Submit an Article

Follow Journal | |

Journal Home | RSC Journals

Communication

Previous Article | Next Article

Synthesis and reactivity of ferrocenyl functionalized Sn/S cages

Christopher Pöhlker , Inga Schellenberg , Rainer Pöttgen and Stefanie Dehnen

Chem. Commun., 2010,46, 2605-2607

DOI: 10.1039/B923871A
Received 13 Nov 2009, Accepted 15 Jan 2010
First published on the web 02 Feb 2010

Please wait while Download options loads

Request Permissions

Abstract
Cited by
Compounds
Related Content

Depending on the solvent used, the mono-stannylated FcSnCl₃ (1) reacts with Na₂S to give ionic [Na₆(Me₂CO)₄(OH₂)₆] [(FcSn)₃S₆]₂ (2), with a yet unprecedented thiostannate anion, or the adamantane-type Sn/S-cluster [(FcSn)₄S₆] (3). Complex 2 reacts readily with [Ni(acac)₂], yielding the mixed-metallic complex [{Na(thf)_3.5}₂{(FcSn)₈Ni₃S₁₆}]·2THF (4·2THF); the structures of 1–4 are discussed as well as Mössbauer spectra.