Issue 13, 2010
From the journal:

Chemical Communications

Tandem Nazarov cyclization–halovinylation of divinyl ketones under Vilsmeier conditions: synthesis of highly substituted cyclopentadienes†

Mang Wang,*a   Feng Han,a   Hongjuan Yuana  and  Qun Liu*a  

* Corresponding authors

a Department of Chemistry, Northeast Normal University, Changchun 130024, China
E-mail: wangm452@nenu.edu.cn
Fax: +86 431 85099759
Tel: +86 431 85099759

Abstract

A new Vilsmeier reagent-mediated Nazarov cyclization–halovinylation reaction of divinyl ketones was developed to provide a straightforward method for the synthesis of highly substituted cyclopentadienes with the advantages of simplicity of execution, readily available substrates, cheap reagents, and broad range of potential products and applications.

Graphical abstract: Tandem Nazarov cyclization–halovinylation of divinyl ketones under Vilsmeier conditions: synthesis of highly substituted cyclopentadienes

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Article information

DOI
https://doi.org/10.1039/B917703E
Article type
Communication
Submitted
27 Aug 2009
Accepted
27 Nov 2009
First published
13 Jan 2010

Chem. Commun., 2010,46, 2247-2249

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Tandem Nazarov cyclization–halovinylation of divinyl ketones under Vilsmeier conditions: synthesis of highly substituted cyclopentadienes

M. Wang, F. Han, H. Yuan and Q. Liu, Chem. Commun., 2010, 46, 2247 DOI: 10.1039/B917703E

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