Issue 8, 2009
From the journal:

New Journal of Chemistry

Polyethylene glycol radical-initiated benzylic C–H bond oxygenation in compressed carbon dioxide†

Jin-Quan Wanga  and  Liang-Nian He*a  

* Corresponding authors

a State Key Laboratory of Elemento-Organic Chemistry, Nankai University, P. R. China
E-mail: heln@nankai.edu.cn
Fax: +86 22 23504216
Tel: +86 22 23504216

Abstract

The PEG radical originating from the thermal/oxidative degradation of PEG in dense CO2 was successfully applied to the oxygenation of benzylic hydrocarbons under organic solvent-free conditions. In addition, in our study, dense CO2 could improve the oxygenation reaction.

Graphical abstract: Polyethylene glycol radical-initiated benzylic C–H bond oxygenation in compressed carbon dioxide

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Article information

DOI
https://doi.org/10.1039/B908993D
Article type
Letter
Submitted
06 May 2009
Accepted
15 Jun 2009
First published
25 Jun 2009

New J. Chem., 2009,33, 1637-1640

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Polyethylene glycol radical-initiated benzylic C–H bond oxygenation in compressed carbon dioxide

J. Wang and L. He, New J. Chem., 2009, 33, 1637 DOI: 10.1039/B908993D

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