The characterization of chloroboron (iii) subnaphthalocyanine thin films and their application as a donor material for organic solar cells

Abstract

Chloroboron (III) subnaphthalocyanine (SubNc) films have been characterized by ellipsometry, absorption, photoluminescence measurements, and atomic force microscopy. The films strongly absorb red light, as the extinction coefficient k peaks at 1.4 at a wavelength of 686 nm. Planar bilayer heterojunctions with fullerene (C₆₀) on top of SubNc are measured under AM 1.5 simulated illumination at various light intensities, leading to an open-circuit voltage (V_oc) of 790 mV and a power conversion efficiency of 2.5%. The external and internal quantum efficiencies peaked at 36% and 70%, respectively. The combination of a strong red absorption and high V_oc make SubNc an interesting material for organic solar cells, in particular for tandem cells.