Issue 11, 2009
From the journal:

Green Chemistry

Water as the medium of choice for the 1,3-dipolar cycloaddition reactions of hydrophobic nitrones

Evdoxia Coutouli-Argyropoulou,*a   Prodromos Sarridisa  and  Petros Gkizisa  

* Corresponding authors

a Laboratory of Organic Chemistry, Chemistry Department, Aristotle University of Thessaloniki 54 124, Thessaloniki, Greece
E-mail: evd@chem.auth.gr
Fax: +30 231-099-7679
Tel: +30 231-099-7733

Abstract

1,3-Dipolar cycloadditions of different hydrophobic nitrones 1, 2, 3, 4 with acrylates 5 and 6 were studied in both homogenous organic solutions and aqueous suspensions. Reactions in water suspensions showed great rate accelerations over homogenous solutions. Small changes were also observed to the stereoselectivities of the reactions. Hydrophobic interactions are invoked for the observed behaviour.

Graphical abstract: Water as the medium of choice for the 1,3-dipolar cycloaddition reactions of hydrophobic nitrones

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B916765J
Article type
Paper
Submitted
27 May 2009
Accepted
10 Aug 2009
First published
17 Sep 2009

Green Chem., 2009,11, 1906-1914

Permissions

Request permissions

Water as the medium of choice for the 1,3-dipolar cycloaddition reactions of hydrophobic nitrones

E. Coutouli-Argyropoulou, P. Sarridis and P. Gkizis, Green Chem., 2009, 11, 1906 DOI: 10.1039/B916765J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements