Retracted Article: Efficient microwave-promoted acrylonitrile sustainable synthesis from glycerol

Vanesa Calvino-Casilda; M. Olga Guerrero-Pérez; Miguel A. Bañares

doi:10.1039/B904689E

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Retracted Article: Efficient microwave-promoted acrylonitrile sustainable synthesis from glycerol

Vanesa Calvino-Casilda,*^a M. Olga Guerrero-Pérez^b and Miguel A. Bañares^a

Author affiliations

* Corresponding authors

^a Catalytic Spectroscopy Laboratory Instituto de Catálisis y Petroleoquímica (CSIC) Marie Curie, Madrid, Spain
E-mail: vcalvino@icp.csic.es
Fax: +34 915 85 47 60

^b Departamento de Ingeniería Química Universidad de Málaga, Málaga, Spain

Abstract

Solvent-free microwave-activation, in the liquid phase using an alumina supported V-Sb-O catalyst, affords highly efficient conversion (47%) of glycerol into acrylonitrile under mild conditions, short reaction times and in the absence of any solvent; in addition, it increases selectivity (>80%) compared to conventional thermal activation.