One-step formation of cyclometallated Au(III) N,S-heterocyclic carbene: crystallographic analysis

Abstract

Gold(I) N,S-heterocyclic carbene AuBr(NSHC) (NSHC = N-allylbenzothiazolin-2-ylidene) (1) with an allyl pendant is oxidised by iodine to give [AuI₂(NSHC)₂]⁺[I₃]⁻ (2) and a cyclometallated byproduct AuBr₂(η-C₆H₄SCNCH₂CHCH₂Br-C,C′) (3). The latter can be prepared directly from bromination of 1. Similar reaction with the crotyl (but-2-en-1-yl) derivative AuBr(NSHC) (NSHC = N-crotylbenzothiazolin-2-ylidene) (4) gives an oxidative addition product AuBr₃(C₆H₄SCNCH₂CHCHCH₃) (5). X-Ray single-crystal crystallographic analysis of 3 reveals a 5-membered cyclometallated ring in a sq planar metal that gives two types of Au^III–C bonds. Similar structural analysis has also been carried out in 1, 2 and 5.