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Issue 23, 2009
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Caesium-templated lanthanoid-containing polyoxotungstates

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A family of novel lanthanoid-containing polytungstoarsenate(III) polyanions with interesting structural features has been isolated: six lacunary {α-AsW9O33} building blocks comprising unusual pyramidal WO5 units are templated by a caesium cation in a central cavity of the structure.

Graphical abstract: Caesium-templated lanthanoid-containing polyoxotungstates

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The article was received on 02 Feb 2009, accepted on 30 Mar 2009 and first published on 16 Apr 2009

Article type: Communication
DOI: 10.1039/B902077B
Citation: Dalton Trans., 2009,0, 4423-4425
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    Caesium-templated lanthanoid-containing polyoxotungstates

    F. Hussain, B. Spingler, F. Conrad, M. Speldrich, P. Kögerler, C. Boskovic and G. R. Patzke, Dalton Trans., 2009, 0, 4423
    DOI: 10.1039/B902077B

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