Issue 17, 2009
From the journal:

Dalton Transactions

A cyclic tetranuclear Ni2Gd2 complex bridged by amino acidato ligands, with an S = 9 ground state, derived from ferromagnetic spin-coupling between nickel(ii) and gadolinium(iii) ions†

Satoshi Igarashi,a   Shin-ichi Kawaguchi,a   Yasuhiko Yukawa,*b   Floriana Tuna*c  and  Richard E. P. Winpennyc  

* Corresponding authors

a Graduate School of Science and Technology, Niigata University, 8050 Ikarashi Nino-cho, Nishi-ku, Niigata, Japan

b Department of Environmental Science, Faculty of Science, Niigata University, 8050 Ikarashi Nino-cho, Nishi-ku, Niigata, Japan
E-mail: yukawa@env.sc.niigata-u.ac.jp
Fax: +81-(0)25-262-6361
Tel: +81-(0)25-262-6361

c Department of Chemistry, The University of Manchester, Oxford Road, Manchester
E-mail: Floriana.Tuna@manchester.ac.uk
Tel: +44 (0)1612 754582

Abstract

Synthesis and structure of a cyclic tetranuclear Ni2Gd2 complex bridged by amino acidato ligands, with an S = 9 spin ground state, derived from ferromagnetic spin-coupling between SGd = 7/2 and SNi = 1 are reported.

Graphical abstract: A cyclic tetranuclear Ni2Gd2 complex bridged by amino acidato ligands, with an S = 9 ground state, derived from ferromagnetic spin-coupling between nickel(ii) and gadolinium(iii) ions

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Article information

DOI
https://doi.org/10.1039/B823366G
Article type
Communication
Submitted
05 Jan 2009
Accepted
12 Feb 2009
First published
24 Feb 2009

Dalton Trans., 2009, 3140-3142

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A cyclic tetranuclear Ni2Gd2 complex bridged by amino acidato ligands, with an S = 9 ground state, derived from ferromagnetic spin-coupling between nickel(II) and gadolinium(III) ions

S. Igarashi, S. Kawaguchi, Y. Yukawa, F. Tuna and R. E. P. Winpenny, Dalton Trans., 2009, 3140 DOI: 10.1039/B823366G

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