The adsorbate structure of ferrocene inside [Al(OH)(bdc)]x (MIL-53): a powder X-ray diffraction study

Mikhail Meilikhov; Kirill Yusenko; Roland A. Fischer

doi:10.1039/B820882B

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The adsorbate structure of ferrocene inside [Al(OH)(bdc)]_x (MIL-53): a powder X-ray diffraction study†

Mikhail Meilikhov,^a Kirill Yusenko^a and Roland A. Fischer*^a

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* Corresponding authors

^a Anorganische Chemie II, Ruhr-Universität Bochum, Universitätsstrasse 150, Bochum, Germany
E-mail: roland.fischer@ruhr-uni-bochum.de
Fax: +49 (0)234 32-14174
Tel: +49 (0)234 32-24174

Abstract

Ferrocene is strongly adsorbed by the highly porous metal-organic framework compound [Al(OH)(bdc)]_x (MIL-53; bdc = 1,4-benzenedicarboxylate). The structure of the crystalline phase {[Fe(η⁵-C₅H₅)₂][Al(OH)(bdc)]₂}_x was determined by X-ray powder diffraction and Rietveld methods. The ferrocene molecules are arranged in a 1D chain-like fashion and their cyclopentadienyl rings are oriented almost parallel to the O₃Al faces of the {AlO₆} octahedra without π-stacking to the bdc.

$Graphical abstract: The adsorbate structure of ferrocene inside [Al(OH)(bdc)]x (MIL-53): a powder X-ray diffraction study$

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Article information

DOI: https://doi.org/10.1039/B820882B
Article type: Communication
Submitted: 06 Oct 2008
Accepted: 21 Nov 2008
First published: 08 Dec 2008

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Dalton Trans., 2009, 600-602

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The adsorbate structure of ferrocene inside [Al(OH)(bdc)]_x (MIL-53): a powder X-ray diffraction study

M. Meilikhov, K. Yusenko and R. A. Fischer, Dalton Trans., 2009, 600 DOI: 10.1039/B820882B

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Dalton Transactions