Issue 8, 2009
From the journal:

CrystEngComm

An organo-ruthenium grafted zinc-substituted tungstoarsenate†

Li-Hua Bi,*a   Guang-Feng Hou,a   Li-Xin Wu*a  and  Ulrich Kortzb  

* Corresponding authors

a State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun, P.R. China
E-mail: bilihua@email.jlu.edu.cn, wulx@jlu.edu.cn
Fax: +86-431-85193421
Tel: +86-431-85168481

b School of Engineering and Science, Jacobs University, P.O. Box 750 561, Bremen, Germany
E-mail: u.kortz@jacobs-university.de
Fax: +49-421-200-3235
Tel: (+49) 421 200 3229

Abstract

An unprecedented organo-ruthenium grafted asymmetric zinc-substituted sandwich-type tungstoarsenate, [{B-α-AsW9O34}{B-β-AsW8O31}{Zn4(OH)2(H2O)2}{(RuC6H6)3}]6− (1) has been synthesized and characterized, representing the fundamentally novel binding mode of Ru-coordination to a polyoxoanion fragment via Ru–O–W, Ru–O–Zn and Ru–O–Zn(W) bonds. Polyanion 1 represents the first example of a structurally characterized transition metal substituted sandwich-type polyoxometalate incorporated with organo-ruthenium.

Graphical abstract: An organo-ruthenium grafted zinc-substituted tungstoarsenate

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Article information

DOI
https://doi.org/10.1039/B905030B
Article type
Communication
Submitted
12 Mar 2009
Accepted
07 May 2009
First published
22 May 2009

CrystEngComm, 2009,11, 1532-1535

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An organo-ruthenium grafted zinc-substituted tungstoarsenate

L. Bi, G. Hou, L. Wu and U. Kortz, CrystEngComm, 2009, 11, 1532 DOI: 10.1039/B905030B

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