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Issue 8, 2009
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An organo-ruthenium grafted zinc-substituted tungstoarsenate

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Abstract

An unprecedented organo-ruthenium grafted asymmetric zinc-substituted sandwich-type tungstoarsenate, [{B-α-AsW9O34}{B-β-AsW8O31}{Zn4(OH)2(H2O)2}{(RuC6H6)3}]6− (1) has been synthesized and characterized, representing the fundamentally novel binding mode of Ru-coordination to a polyoxoanion fragment via Ru–O–W, Ru–O–Zn and Ru–O–Zn(W) bonds. Polyanion 1 represents the first example of a structurally characterized transition metal substituted sandwich-type polyoxometalate incorporated with organo-ruthenium.

Graphical abstract: An organo-ruthenium grafted zinc-substituted tungstoarsenate

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Publication details

The article was received on 12 Mar 2009, accepted on 07 May 2009 and first published on 22 May 2009


Article type: Communication
DOI: 10.1039/B905030B
Citation: CrystEngComm, 2009,11, 1532-1535
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    An organo-ruthenium grafted zinc-substituted tungstoarsenate

    L. Bi, G. Hou, L. Wu and U. Kortz, CrystEngComm, 2009, 11, 1532
    DOI: 10.1039/B905030B

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