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Issue 40, 2009
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Asymmetric β-boration of α,β-unsaturated carbonyl compounds promoted by chiral rhodium–bisoxazolinylphenyl catalysts

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Abstract

Chiral rhodium–bisoxazolinylphenyl acetate complexes exhibited high catalytic activity for the β-boration of α,β-unsaturated carbonyl compounds with bis(pinacolato)diboron in the presence of sodium t-butoxide with enantioselectivity up to 97%.

Graphical abstract: Asymmetric β-boration of α,β-unsaturated carbonyl compounds promoted by chiral rhodium–bisoxazolinylphenyl catalysts

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Publication details

The article was received on 31 Jul 2009, accepted on 09 Sep 2009 and first published on 16 Sep 2009


Article type: Communication
DOI: 10.1039/B915759J
Citation: Chem. Commun., 2009,0, 5987-5989
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    Asymmetric β-boration of α,β-unsaturated carbonyl compounds promoted by chiral rhodium–bisoxazolinylphenyl catalysts

    T. Shiomi, T. Adachi, K. Toribatake, L. Zhou and H. Nishiyama, Chem. Commun., 2009, 0, 5987
    DOI: 10.1039/B915759J

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