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Issue 37, 2009
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Barriers to enantiocontrol in Lewis acid catalyzed hetero-Diels–Alder reactions

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Abstract

Lewis bases, including reactant aldehydes, inhibit the rate of conversion for cycloaddition and those, like aldehydes or nitriles, cause a decrease in enantiocontrol due to the Lewis acidity of the activated complex.

Graphical abstract: Barriers to enantiocontrol in Lewis acid catalyzed hetero-Diels–Alder reactions

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Publication details

The article was received on 01 Jul 2009, accepted on 14 Aug 2009 and first published on 26 Aug 2009


Article type: Communication
DOI: 10.1039/B913019E
Citation: Chem. Commun., 2009,0, 5612-5614
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    Barriers to enantiocontrol in Lewis acid catalyzed hetero-Diels–Alder reactions

    X. Wang, Z. Li and M. P. Doyle, Chem. Commun., 2009, 0, 5612
    DOI: 10.1039/B913019E

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