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Issue 36, 2009
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Copper-catalyzed enantioselectivecarbenoidinsertion into S–H bonds

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Abstract

An asymmetriccarbenoidinsertion into S–H bonds catalyzed by copper–chiral spiro bisoxazoline complexes has been developed, in which a series of α-mercaptoesters were produced in high yields with moderate to good enantioselectivities (up to 85% ee); this result represents the best enantioselectivity in the catalytic asymmetriccarbenoid S–H bond insertion reaction.

Graphical abstract: Copper-catalyzed enantioselectivecarbenoidinsertion into S–H bonds

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Publication details

The article was received on 16 Jun 2009, accepted on 22 Jul 2009 and first published on 11 Aug 2009


Article type: Communication
DOI: 10.1039/B911670B
Citation: Chem. Commun., 2009, 5362-5364
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    Copper-catalyzed enantioselectivecarbenoidinsertion into S–H bonds

    Y. Zhang, S. Zhu, Y. Cai, H. Mao and Q. Zhou, Chem. Commun., 2009, 5362
    DOI: 10.1039/B911670B

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